Molecular Thermodynamics and Transport Phenomena by Michael H. Peters

Author:Michael H. Peters [Peters, Michael H.]
Language: ita
Format: epub
Published: 0101-01-01T00:00:00+00:00

1

n 2(r1, r2, t) =

nN (r N , t) d r N −2

(4.47)

( N − 2)!

We next examine specific forms of the thermodynamic basis functions

( U, SG, P) under equilibrium conditions. †

4.4

Determination of the Configurational

Distribution Functions

In order to compute the thermodynamic properties, the many-bodied

configurational distribution nN (r N ) is needed. An approximate method

of treating many-bodied interactions is the assumption of pairwise ad-

ditivity, i.e., the total potential is written as

1

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